[root@localhost tftpboot]# nano /etc/sysconfig/network-scripts/route-eth0


GATEWAY0=172.33.55.16

NETMASK0=255.255.0.0

ADDRESS0=10.5.0.0

GATEWAY1=172.33.55.16

NETMASK1=255.255.0.0

ADDRESS1=10.100.0.0


Save it with CTRL + O.

Exit with CTRL + X 


You can do a test by rebooting the network service using the command below:

service network restart


If you see the routes like below, you are good to go. 

[root@localhost tftpboot]# route -n 

Kernel IP routing table

Destination     Gateway         Genmask         Flags Metric Ref    Use Iface

172.33.55.0     0.0.0.0         255.255.255.0   U     0      0        0 eth0

10.100.0.0      172.33.55.16    255.255.0.0     UG    0      0        0 eth0

10.5.0.0        172.33.55.16    255.255.0.0     UG    0      0        0 eth0

169.254.0.0     0.0.0.0         255.255.0.0     U     1002   0        0 eth0

0.0.0.0         172.33.55.254   0.0.0.0         UG    0      0        0 eth0

[root@localhost tftpboot]#